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A new stereoselective synthesis of (Z)-vinylsilane allylic alcohols

Kim, Kee D. ; Magriotis, Plato A.

Tetrahedron Letters, 1990, Vol.31(43), pp.6137-6140 [Peer Reviewed Journal]

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  • Title:
    A new stereoselective synthesis of (Z)-vinylsilane allylic alcohols
  • Author: Kim, Kee D. ; Magriotis, Plato A.
  • Description: A new, highly stereoselective method for the synthesis of (Z)-vinylsilane allylic alcohols 3 is described. This approach to such γ-silylated allylic alcohols employs a novel 1,4-0→sp 2 C silyl rearrangement of appropriate silyl ether precursors 2 . A highly stereoselective synthesis of the title compounds (γ-silylated allylic alcohols, R 2 =H) is described employing a novel 1,4-0→sp 2 C silyl rearrangement.
  • Is Part Of: Tetrahedron Letters, 1990, Vol.31(43), pp.6137-6140
  • Identifier: ISSN: 0040-4039 ; DOI: 10.1016/S0040-4039(00)97007-2
  • Language: English
  • Source: ScienceDirect (Elsevier B.V.)

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