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A highly selective synthesis of versatile (E)-1-phenylthio vinylstannanes

Magriotis, Plato A. ; Brown, John T. ; Scott, Mary E.

Tetrahedron Letters, 1991, Vol.32(38), pp.5047-5050 [Peer Reviewed Journal]

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  • Title:
    A highly selective synthesis of versatile (E)-1-phenylthio vinylstannanes
  • Author: Magriotis, Plato A. ; Brown, John T. ; Scott, Mary E.
  • Description: An efficient, palladium-catalyzed hydrostannation of 1-phenylthio-1-alkynes 1 is described. This novel tributyltin hydride addition provides versatile 1-phenylthio vinylstannanes 2 regio- and stereoselectively. A regio- and stereoselective synthesis of the title compounds is described employing efficient Pd(0)-catalyzed addition of Bu 3 SnH and possessing wide scope ( R group).
  • Is Part Of: Tetrahedron Letters, 1991, Vol.32(38), pp.5047-5050
  • Identifier: ISSN: 0040-4039 ; DOI: 10.1016/S0040-4039(00)93424-5
  • Subjects: Hydrostannation ; Palladium(O) ; Tributyltin Hydride ; 1-Phenylthio-1-Alkynes ; (E)-1-Phenylthio Vinylstannanes
  • Language: English
  • Source: ScienceDirect (Elsevier B.V.)

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