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14N ENDOR of the nitrobenzene radical anion in solution

Lendzian, F ; Plato, M ; Möbius, K

Journal of Magnetic Resonance (1969), 1981, Vol.44(1), pp.20-31

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  • Title:
    14N ENDOR of the nitrobenzene radical anion in solution
  • Author: Lendzian, F ; Plato, M ; Möbius, K
  • Description: A quantitative test of ENDOR theory for free radicals in solution is performed on the 14 N nucleus of the nitrobenzene radical anion in dimethoxyethane. Dominant relaxation contributions are caused by modulation of the electron nuclear dipolar interaction. They can be calculated from the known G and 14 N hyperfine tensors of the nitrobenzene radical anion. The effects of spin-rotation interaction and Heisenberg spin exchange at different concentrations are investigated experimentally and theoretically. The concentration and temperature dependences of the 14 N ENDOR amplitudes are found to agree well with theoretical predictions.
  • Is Part Of: Journal of Magnetic Resonance (1969), 1981, Vol.44(1), pp.20-31
  • Identifier: ISSN: 0022-2364 ; E-ISSN: 1557-8968 ; DOI: 10.1016/0022-2364(81)90185-2
  • Subjects: Physics
  • Language: English

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