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Steroids I. Alkylation of β-ketoesters via their Cu(II) enolates in aqueous media. Application of the synthesis of C-18 functionalized steroids via the torgov approach.

Magriotis, Plato A. ; Murray, William V. ; Johnson, Francis

Tetrahedron Letters, 1982, Vol.23(19), pp.1993-1996 [Peer Reviewed Journal]

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  • Title:
    Steroids I. Alkylation of β-ketoesters via their Cu(II) enolates in aqueous media. Application of the synthesis of C-18 functionalized steroids via the torgov approach.
  • Author: Magriotis, Plato A. ; Murray, William V. ; Johnson, Francis
  • Description: Three steroidal pentaenes ( 8 ˜ a− c ˜ ) have been synthesized, the key step being the alkylation of the Cu(II) chelates to the ring D precursors ( 3 ˜ − 5 ˜ ) by the isothiouronium acetate 1 ˜ in aqueous solution.
  • Is Part Of: Tetrahedron Letters, 1982, Vol.23(19), pp.1993-1996
  • Identifier: ISSN: 0040-4039 ; DOI: 10.1016/S0040-4039(00)87242-1
  • Subjects: Chemistry
  • Language: English

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