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A novel approach to the synthesis of enediynes

Magriotis, Plato A. ; Scott, Mary E. ; Kim, Kee D.

Tetrahedron Letters, 1991, Vol.32(43), pp.6085-6088 [Peer Reviewed Journal]

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  • Title:
    A novel approach to the synthesis of enediynes
  • Author: Magriotis, Plato A. ; Scott, Mary E. ; Kim, Kee D.
  • Description: A new method for the synthesis of enediynes is described based on stannylcupration of acetylene and certain activated alkynes, in situ reaction with 1-halo-1-alkynes, iododestannylation, and Pd(0)-catalyzed coupling with terminal alkynes. A new method for the synthesis of enediynes is described based on stannylcupration of acetylene and certain activated alkynes, in situ reaction with 1-halo-1-alkynes to provide stannyl enynes (45–75%), iododestannylation, and coupling with terminal alkynes.
  • Is Part Of: Tetrahedron Letters, 1991, Vol.32(43), pp.6085-6088
  • Identifier: ISSN: 0040-4039 ; DOI: 10.1016/0040-4039(91)80759-Y
  • Subjects: Stannylcupration ; 1-Phenylthio-1-Alkynes ; Vinylcopper-Zinc Intermediates ; Stannyl Enynes ; Enediynes
  • Language: English
  • Source: ScienceDirect (Elsevier B.V.)

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