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Transition-metal-free synthesis of oxindoles by potassium tert-butoxide-promoted intramolecular α-arylation

Beyer, Astrid ; Buendia, Julien ; Bolm, Carsten

Organic letters, 03 August 2012, Vol.14(15), pp.3948-51 [Peer Reviewed Journal]

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  • Title:
    Transition-metal-free synthesis of oxindoles by potassium tert-butoxide-promoted intramolecular α-arylation
  • Author: Beyer, Astrid ; Buendia, Julien ; Bolm, Carsten
  • Description: Potassium tert-butoxide-mediated intramolecular α-arylations of fluoro- and chloro-substituted anilides provide oxindoles in DMF at 80 °C. In this manner, diversely substituted products have been obtained in moderate to high yields.
  • Is Part Of: Organic letters, 03 August 2012, Vol.14(15), pp.3948-51
  • Identifier: E-ISSN: 1523-7052 ; PMID: 22794114 Version:1 ; DOI: 10.1021/ol301704z
  • Subjects: Anilides -- Chemistry ; Butanols -- Chemistry ; Indoles -- Chemical Synthesis
  • Language: English
  • Source: MEDLINE/PubMed (U.S. National Library of Medicine)
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