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Observation of quadrupole splittings of organic radicals in solution by endor in liquid crystals

Dinse, K.P. ; Möbius, K. ; Plato, M. ; Biehl, R. ; Haustein, H.

Chemical Physics Letters, 1972, Vol.14(2), pp.196-200 [Peer Reviewed Journal]

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  • Title:
    Observation of quadrupole splittings of organic radicals in solution by endor in liquid crystals
  • Author: Dinse, K.P. ; Möbius, K. ; Plato, M. ; Biehl, R. ; Haustein, H.
  • Description: Quadrupole splittings of organic nitroxide radicals in solution have been observed by ENDOR in a liquid crystal. The analysis of the line shifts yields e 2 q ′ 33 Q/h = −2.5 MHz. This result could be rationalized by a population analysis of the nitrogen bonds. The theory predicts that the main contribution to the observed splitting comes from the unpaired π-electron.
  • Is Part Of: Chemical Physics Letters, 1972, Vol.14(2), pp.196-200
  • Identifier: ISSN: 0009-2614 ; DOI: 10.1016/0009-2614(72)87177-X
  • Language: English
  • Source: ScienceDirect (Elsevier B.V.)

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