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Catalytic asymmetric hydrogenation to access spiroindane dimethyl acetic acid

He, Shuwen ; Shultz, C. Scott ; Lai, Zhong ; Eid, Ronsar ; Dobbelaar, Peter H ; Ye, Zhixiong ; Nargund, Ravi P

Tetrahedron Letters, 13 July 2011, Vol.52(28), pp.3621-3624 [Peer Reviewed Journal]

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  • Title:
    Catalytic asymmetric hydrogenation to access spiroindane dimethyl acetic acid
  • Author: He, Shuwen ; Shultz, C. Scott ; Lai, Zhong ; Eid, Ronsar ; Dobbelaar, Peter H ; Ye, Zhixiong ; Nargund, Ravi P
  • Description: Asymmetric hydrogenation of achiral spiroindene dimethyl acetic acid with 4% of Ru(II)-Mandyphos in acetone produced ( )-spiroindane dimethyl acetic acid in 86% isolated yield and 96.8:3.2 enantiomeric ratio. Asymmetric hydrogenation of achiral spiroindene dimethyl acetic acid with 4% of Ru(II)-Mandyphos in acetone produced ( )-spiroindane dimethyl acetic acid in 86% isolated yield and 96.8:3.2 enantiomeric ratio.
  • Is Part Of: Tetrahedron Letters, 13 July 2011, Vol.52(28), pp.3621-3624
  • Identifier: ISSN: 0040-4039 ; E-ISSN: 1873-3581 ; DOI: 10.1016/j.tetlet.2011.05.029
  • Subjects: Asymmetric Hydrogenation ; Ruthenium ; Chiral Phosphine ; Spiroindane ; Chemistry
  • Language: English
  • Source: ScienceDirect Journals (Elsevier)

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