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Stereoselective construction and synthetic applications of phenylthio substituted iodoolefins

A. Magriotis, Plato ; J. Doyle, Timothy ; D. Kim, Kee

Tetrahedron Letters, 1990, Vol.31(18), pp.2541-2544 [Peer Reviewed Journal]

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  • Title:
    Stereoselective construction and synthetic applications of phenylthio substituted iodoolefins
  • Author: A. Magriotis, Plato ; J. Doyle, Timothy ; D. Kim, Kee
  • Description: (E)- and (Z)-Phenylthio substituted iodoolefins 1 and 2 have been synthesized stereoselectively via lower order stannylcuprate addition to and hydroalumination of appropriate alkyne precursors. Their utility in model studies on the synthesis of calichemicin/esperamicin and neocarzinostatin aglycones is shown. (E)- and (Z)-Phenylthio substituted iodoolefins 1 and 2 have been synthesized stereoselectively. Their utility in model studies on the synthesis of calichemicin/esperamicin and neocarzinostatin aglycones is shown.
  • Is Part Of: Tetrahedron Letters, 1990, Vol.31(18), pp.2541-2544
  • Identifier: ISSN: 0040-4039 ; E-ISSN: 1873-3581 ; DOI: 10.1016/0040-4039(90)80120-B
  • Subjects: Chemistry
  • Language: English

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