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Structural characterization of the primary donor in photosynthetic bacteria by its electronic g-tensor

Plato, M ; Möbius, K

Chemical Physics, 1995, Vol.197(3), pp.289-295 [Peer Reviewed Journal]

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  • Title:
    Structural characterization of the primary donor in photosynthetic bacteria by its electronic g-tensor
  • Author: Plato, M ; Möbius, K
  • Description: Semiempirical molecular orbital calculations of the electronic g -tensor have been performed on the primary donor cation radical P 865 +· of Rb. sphaeroides R-26 reaction centers (RCs). These calculations are based on Stone's theory for free radical doublet states and RHF-INDO wave functions and orbital energies. The result is in qualitative agreement with recent W-band (95 GHz) EPR measurements of the g -tensor in RC single crystals which show a breaking of C 2 symmetry in the primary donor electronic structure.
  • Is Part Of: Chemical Physics, 1995, Vol.197(3), pp.289-295
  • Identifier: ISSN: 0301-0104 ; DOI: 10.1016/0301-0104(95)00106-X
  • Subjects: Chemistry ; Physics
  • Language: English

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